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Synopsis : This course introduces chemical engineering thermodynamic theory and applications in the areas of volumetric properties of fluids, heat effects, thermodynamic properties of fluids, thermodynamics of solutions, and physical and chemical equilibria.
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Introduction to Chemical Engineering Thermodynamic
Volumetric Properties of Pure Fluids
o Ideal gas equation
o Virial equation
o Generic cubic equations
o Gases
It is expected that students will have the ability to: .
· Determine the state/phase of a given fluid at given conditions.
· Compare and contrast the various equations of state and generalized correlations.
· Identify the applicability and limitation of every equation of state.
· Determine the volumetric properties from thermodynamic tables and diagrams.
Heat Effects
· Introduction to different types of heat effects in thermodynamics
· Sensible heat and heat capacity
o Constant-volume heat capacity
o Constant-pressure heat capacity
o The temperature dependency of the heat capacity
· Latent heat
o Introduction to different types of latent heat
o Latent heat calculations and estimations.
· Standard heat of reaction
o Calculation using standard heat of formations
· Example of Heat effects of industrial reactions
It is expected that students will have the ability to:
· Differentiate the different types of heat effects and their importance in chemical engineering.
· Calculate the enthalpy change for ideal fluids at any given conditions
· Construct the hypothetical path for enthalpy change calculations.
· Calculate the heat transfer to/from the system that involves in the physical or chemical processes.
· Apply the enthalpy calculation in the energy balance for open and closed systems.
Thermodynamic Properties of Fluids
It is expected that students will have the ability to:
· Derive and apply the relation of the canonical parameters (e.g. T and P) and thermodynamic properties (e.g. H, U, S, and G).
· Estimate the entropy and enthalpy for the real fluid using residual properties.
Solution Thermodynamics: Theory
It is expected that students will have the ability to:
· Define and describe the important of the thermodynamic terms such as partial and residual properties, fugacity and fugacity coefficient in chemical engineering.
Differentiate the difference between pure, partial, and solution properties.Solution Thermodynamics: Application
o Fugacity and fugacity coefficient
o Activity and activity coefficient
o Excess Gibbs energy and activity coefficient
o Models for excess Gibbs energy
o Heat of solution
Enthalpy/concentration DiagramIt is expected that students will have the ability to:
solution.
Physical Equilibria
It is expected that students will have the ability to:
Chemical Reaction Equilibria
· Application of equilibrium criteria to chemical reactions
It is expected that students have the ability to: